ORIGINAL_ARTICLE
Iron (III) Phosphate Catalyzed the Synthesis of 4-quinolones
New and efficient methods have been developed for the synthesis of 4-quinolones throughout Conrad–Limpach synthesis in diphenyl ether under reflux condition. This method possesses various advantages such as using a green and versatile catalyst, easy procedure, work up and separation, being free from column chromatography, and atom economic. Also, this kind of solvent and the reaction temperature has an important role in the yield of reaction. When toluene, ethanol, acetonitrile and chloroform were subjected as solvent in ambient temperature and reflux condition, the desired product did not result. Moreover, when diphenyl ether was employed in room temperature – at 100, 150 and 200 °C – it was observed that the product was obtained. Interestingly, the desired product was obtained in good yield under reflux condition in diphenyl ether.
https://www.chemmethod.com/article_60161_a8efab7c987d678784609f0be8e4b63b.pdf
2018-07-01
181
185
10.22034/chemm.2018.60161
4-Quinolones
Synthesis
Catalyst
Iron (III) phosphate
Samaneh
Samadi
chemist.200710@yahoo.com
1
Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran.
AUTHOR
Farahnaz
K. Behbahani
farahnazkargar@yahoo.com
2
Department of Chemistry, Karaj Branch, Islamic Azad University, Karaj, Iran.
LEAD_AUTHOR
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10
ORIGINAL_ARTICLE
Cyclic Voltammetry of Zirconyl Chloride (ZrOCl2) in KF Medium Using Silver Working Electrode (SWE)
The cyclic Voltammetry of zirconyl chloride with different concentrations was measured experimentally using DY2000 cyclic Voltammetry apparatus in 0.1M KF (potassium fluoride) as a supporting electrolyte. The silver electrode was used as a supporting working electrode. The other two electrodes in the three-electrode system are platinum wire and Ag / AgCl electrode immersed in saturated KCl solution. The redox mechanism was supported by reduction and/or oxidation. Effect of scan rate was also examined and the redox system is diffusion controlled.The different used scans are 0.1,0.02 and 0.01 Volt per Sec. The relation between iP and log scan rate was done to ensure the redox mechanism.It was concluded that zirconyl ions are hydrolyzed in 0.1M KF solutions forming hydroxyl complexes.
https://www.chemmethod.com/article_60859_9fc3cbfe32ec3b09ff2b083d562de689.pdf
2018-07-01
186
193
10.22034/chemm.2018.60859
Cyclic Voltammetry
zirconyl chloride
potassium fluoride electrolyte
Solvation parameters
silver working electrode
Esam A.
Gomaa
eahgomaa65@yahoo.com
1
Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt
LEAD_AUTHOR
Anwer
G. Al- Harazie
2
Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt
AUTHOR
Mahmoud
N.Abdel-Hady
3
Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt
AUTHOR
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1
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[5] Gomaa E.A., Amer. J.Polymer Sci., 2012, 23:35-47
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6
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15
ORIGINAL_ARTICLE
Selective Transport of Aromatic Compounds across Parchment Supported Prussian blue Membrane
The study of permeation of Aromatic compounds across parchment-supported membrane treated with Prussian blue is presented. The skin layer of the metal hexacyanoferrate membrane consists of a network structure could be selectively used with defined pore size in the nanometer range to permeate molecules with different size molecules. In order to demonstrate a possible sieving of molecules, we have investigated the permeation of a variety of aromatic compounds such as aniline (An), phenol (Ph), and naphthalene (Np). For these neutral compounds, a size-selective transport was found. Size lead to a separation factor α(An/Ph) of 1.5 and α(An/Np) of 4 respectively. Finally, it is demonstrated that purely inorganic membrane of Prussian Blue (PB) can be prepared upon adsorption of ferric ion and hexacyanoferrate on porous support.
https://www.chemmethod.com/article_60860_c2991682228db3baa75d07a6f5550055.pdf
2018-07-01
194
203
10.22034/chemm.2018.60860
selective transport
parchment supported
aromatic molecules
Ashraf
El Hashani
aiiya600@yahoo.co.uk
1
Chemistry Department, Faculty of Science, University of Benghazi, Benghazi, Libya
AUTHOR
Nura
Ben Khayal
hana5912@yahoo.co.uk
2
Chemistry Department, Faculty of Science, University of Benghazi, Benghazi, Libya
AUTHOR
Khaled Muftah
Elsherif
elsherif27@yahoo.com
3
Chemistry Department, Faculty of Science, University of Benghazi, Benghazi, Libya
LEAD_AUTHOR
[1] Tieke B., van Ackern F., Krasemann L., Toutianoush A. Eur. Phys. J., 2001, E5:29
1
[2] Bruening M., Multilayer Thin Films,in G. Decher, J. B. Schlenoff (Eds.), Wiley-VCH, Weinheim 2003, 487-510
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6
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[8] Krasemann L., Tieke B. Langmuir, 2000, 16:287
8
[9] Elsherif K.M., El-Hashani A., El-Dali A. J.App. Chem., 2013, 2:1543
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[10] Toutianoush A., Jin W., Deligöz H., Tieke B. Appl. Surf. Sci., 2005, 146:437
10
[11] Elsherif K.M., Yaghi M.M. J.Materials Environ.Sci., 2017, 8:356
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[18] Toutianoush A., Tieke B. Interf. Sci. Ser., 2001, 11:416
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[19] Toutianoush A., Schnepf J., El-Hashani A., Tieke B. Adv. Funct. Mater., 2005, 15:700
19
[20] Toutianous A., El-Hashani A., Schnep J., Tieke B. Appl. Surf. Sci., 2006, 246:430
20
[21] Elsherif K.M., El-Hashani A., El-Dali A., Musa M. Int. J.Anal.Bioanal. Chem., 2014, 4:58
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[22] Elsherif K.M., El-Hashani A., El-Dali A., Saad M. Int. J. Chem. Pharm. Sci., 2014, 2:890
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[24] Perret F., Bonnard V., Danylyuk O., Suwinska Coleman K. New J. Chem., 2006, 30: 987
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[25] Tieke B., El-Hashani A., Toutianoush A., Fendt A. Thin Solid Films, 2008, 516:8814
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[26] El-Hashani A., Toutianoush A., Tieke B. J. Membr. Sci., 2008, 318:65
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[27] Hoffmann K., El-Hashani A., Tieke B. Macromol. Symp., 2010, 287:22
27
[28] Tieke B., El-Hashani A., Hoffmann K., Maier A. Electrostatic and Coordinative Supramolekular Assembly of Functional Films for Electronic Application and Materials Separation, in Multilayer Thin Films, Sequential Assembly of Nanocomposite Materials, (G. Decher, J.B. Schlenoff, Herausgeber) Wiley-VCH, Weinheim, 2012, S. 473-509
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[29] El-Hashani A., Tieke B. Adv. Materials Res., 2013, 685:378
29
ORIGINAL_ARTICLE
On The Characterization, Utilization and Wastewater Detoxification Potential of Pyrolysed Moringa oleifera Pods and Shells PART A: Sorbent Preparation and Characterization
In part A of this research, we reported adsorbent generation, characterization and optimization of factors affecting sorption. Destructive distillation technique was carried out for transforming biomass into biosorbents. Pyrolysed Moringa oleifera Pods (PMOP) and Shells (PMOS) were used. Adsorbents were characterized for surface morphology, crystallographic pattern, active functional sites and elemental composition using SEM, TEM, PXRD, FTIR and CHNS/O analyzer respectively. Performance assessment of adsorbent was based on removal efficiency. The effect of pH, early adsorbate concentration, contact time, adsorbent dose and temperature on chromium uptake was studied in column mode. Results show the role of both physical and chemical characteristics of the adsorbents. The maximum adsorption capacity of PMOS is 277.3 mg/g. Performance of derived sorbent compared with commercially available activated carbon shows no statistical significance at p< 0.05.
https://www.chemmethod.com/article_61056_7d1815f97637989d2e7500051f33d79f.pdf
2018-07-01
204
222
10.22034/chemm.2018.61056
Moringa oleifera
Characterization
Pods
Shells
Adsorption
PXRD
CHNS/O
Adams Udoji
Itodo
itodoson2002@gmail.com
1
Department of Chemistry, Federal University of Agriculture Makurdi, Nigeria
LEAD_AUTHOR
Raymond Ahulle
Wuana
raynewton73@gmail.com
2
Department of Chemistry, Federal University of Agriculture Makurdi, Nigeria
AUTHOR
Patience Ngunan
Wombo
ngunanwombo@gmail.com
3
Department of Chemistry, Federal University of Agriculture Makurdi, Nigeria
AUTHOR
[1] Hsu R., Midcap S., Arbainsyah D., Witte L. National Herbarium, Leiden, 2006
1
[2] Ho S.Y., McKay G. Canadian Journal of Chem. Eng., 1994, 76:822
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[3] Aslam M.F., Anwar R., Nadeem U., Rashid T.G., Kazi A., Nadeem M. Asian Journal of Plant Science, 2005, 4:417
3
[4] Healthline, Healthline Bulletin, 2005
4
[5] Demirbas E., Kobya M., Sulak M.T. Bioresources Technol., 2008, 99:5368
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[6] Itodo A.U., Abdulrahaman F.W., Hassan L.G., Maigandi S.A., Hapiness U.O., Iran. J. Chem. Chem. Eng, 2011, 30:51
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[7] Abdulrazak S., Sulyman Y.I, Bello H.I. Bello, Akanni A.S., Oniwapele Y.A., Muktari M. J. Environ. Sci. Toxicol. Food Technol. 2015, 9:96
7
[8] Kawse A.M., Monika D., Islam M.M., Mosammat S.A., Shahidul I., Muhammad A.A-M. World Applied Sciences Journal, 2011, 12:152
8
[9] Islam B.I., Musa A.E., Ibrahim E.H., Salma A.A.Sh., Babiker M.E. Journal of Forest Products & Industries, 2014, 3:141
9
[10] APHA American Public Health Association, American Water Works Association, and Water Environment Federation, Washington, DC
10
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[31] Chen J.J., Chen Y.T., Raja. D.S., Kang Y.N., Tseng P.C., Lin C.H., Materials, 2015, 8:5336
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40
ORIGINAL_ARTICLE
Insight into the Stability, Reactivity, Structural and Spectral Properties of the Anti, Syn-endo and Syn-exo Isomers of Bis(N-ethoxy-N-ethyl-dithiocarbamato)Nitrido Technetium-99m [99mTc-N(NOEt)2] Radiopharmaceutical
(Ethoxy(ethyl)amino)methanedithiol is used in nuclear medicines as a ligand for the preparation of diagnostic radiopharmaceuticals. Among the available radionuclide tracers, technetium-99m (99mTc) is a good choice for myocardial perfusion imaging. Among the various cardiac perfusion imaging agents, bis(N-ethoxy-N-ethyl-dithiocarbamato)nitride technetium-99m radiopharmaceutical has a very high uptake. During the present study, the reactivity, stability, structural and spectral properties of anti, syn-endo and syn-exo isomers of bis(N-ethoxy-N-ethyl-dithiocarbamato)nitride technetium-99m radiopharmaceutical were discussed by density functional theory (DFT) computational method. It can be deduced from the theoretically applied computations that the anti- molecular structure is generally more stable than the syn-endo- and syn-exo- ones.
https://www.chemmethod.com/article_62758_2b8fa7eb87de68a668a07763e8055e53.pdf
2018-07-01
223
238
10.22034/chemm.2018.62758
Coronary Artery Disease
Density functional theory
Nuclear medicine
Radiopharmaceutical
99mTc-N(NOEt)2
Mehdi
Nabati
mnabati@ymail.com
1
Synthesis and Molecular Simulation Laboratory, Chemistry Department, Pars Isotope Company, P.O. Box: 1437663181, Tehran, Iran
LEAD_AUTHOR
[1]. Nabati M., Mahkam M. Iran Chem. Commun., 2014, 2:129
1
[2]. Fagret D., Ghezzi C., Vanzetto G. J. Nucl. Med., 2001, 42:1395
2
[3]. Hatada K., Riou L.M., Ruiz M., Yamamichi Y., Duatti A., Lima R.L., Goode A.R., Watson D.D., Beller G.A., Glover D.K. J. Nucl. Med., 2004, 45:2095
3
[4]. Nabati M. Iran. J. Org. Chem., 2017, 9:2045
4
[5]. Takahana K., Beller G.A., Ruiz M., Petruzella F.D., Watson D.D., Glover D.K. J. Nucl. Med., 2001, 42:1388
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[6]. Nabati M., Salehi H. Iran. J. Org. Chem., 2017, 9:2013
6
[7]. Nabati M., Mofrad M.H., Kermanian M., Sarshar S. Iran. J. Org. Chem., 2017, 9:1981
7
[8]. Nabati M., Kermanian M., Maghsoudloo-Mahalli A., Sarshar S. Iran. J. Org. Chem., 2017, 9:2067
8
[9]. Hernandez-Valdes D., Blanco-Gonzalez A., Garcia-Fleitas A., Rodriguez-Riera Z., Meola G., Alberto R., Jauregui-Haza U. J. Mol. Graph. Model., 2017, 71:167
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[10]. Lamb J., Holland J.P. J. Nucl. Med., 2018, 59:382
10
[11]. Dijk J.D.V., Jager P.L., Osch J.A.C.V., Dalen J.A.V. J. Nucl. Med., 2017, 58:518
11
[12]. Nabati M., Kermanian M., Mohammadnejad-Mehrabani H., Kafshboran H.R., Mehmannavaz M., Sarshar S. Chem. Method., 2018, 3:132
12
[13]. Nabati M. Chem. Method., 2017, 2:128
13
[14]. Hernandez-Valdes D., Alberto R., Jauregui-Haza U. RSC Adv., 2016, 6:107127
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[15]. Nabati M. Iran. J. Org. Chem., 2018, 10:2291
15
[16]. Renaud J.M., Yip K., Guimond J., Trottier M., Pibarot P., Turcotte E., Maguire C., Lalonde L., Gulenchyn K., Farncombe T., Wisenberg G., Moody J., Lee B., Port S.C., Turkington T.G., Beanlands R.S., DeKemp R.A. J. Nucl. Med., 2017, 58:103
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[17]. Nabati M., Maghsoudloo-Mahalli A., Mohammadnejad-Mehrabani H., Movahed-Tazehkand H. Iran. J. Org. Chem., 2018, 10:2281
17
[18]. Cittanti C., Uccelli L., Pasquali M., Boschi A., Flammia C., Bagatin E., Casali M., Stabin M.G., Feggi L., Giganti M., Duatti A. J. Nucl. Med., 2008, 49:1299
18
[19]. Nabati M., Maghsoudloo-Mahalli A. Iran. J. Org. Chem., 2017, 9:2239
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[20]. Bolzati C., Cavazza-Ceccato M., Agostini S., Refosco F., Yamamichi Y., Tokunaga S., Carta D., Salvarese N., Bernardini D., Bandoli G. Bioconjugate Chem., 2010, 21:928
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[21]. Nabati M., Mohammadnejad-Mehrabani H. Iran. J. Org. Chem., 2017, 9:2117
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[22]. Maria L., Soares M., Santos I.C., Sousa V.R., Mora E., Marcalo J., Luzyanin K.V. Dalton Trans., 2016, 45:3778
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[23]. Nabati M., Mahkam M. Org. Chem. Res., 2016, 2:70
23
[24]. Nabati M. Iran. J.Org. Chem., 2016, 8:1935
24
[25]. Nabati M., Mahkam M. J. Phys. Theor. Chem., 2015, 12:121
25
[26]. Nabati M. J. Phys. Theor. Chem., 2015, 12:325
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[27]. Nabati M. J. Phys. Theor. Chem., 2017, 14:49
27
[28]. Nabati M., Mahkam M. J. Phys. Theor. Chem., 2015, 12:33
28
[29]. Nabati M., Mahkam M., Atani Y.G. J. Phys. Theor. Chem., 2016, 13:35
29
[30]. Nabati M. J. Phys. Theor. Chem., 2016, 13:133
30
[31]. Moura C., Gano L., Mendes F., Raposinho P.D., Abrantes A.M., Botelho M.F., Santos I., Paulo A. Eur. J. Med. Chem., 2012, 50:350
31
[32]. Nabati M., Mahkam M. Inorg. Chem. Res., 2016, 1:131
32
[33]. Nabati M., Mahkam M. Silicon, 2016, 8:461
33
[34]. Nabati M. Iran. J. Org. Chem., 2015, 7:1631
34
[35]. Qian W., Zhang W., Zong H., Gao G., Zhou Y., Zhang C. J. Mol. Model., 2016, 22:9
35
[36]. Nabati M. Iran. J. Org. Chem., 2015, 7:1669
36
[37]. Nabati M. Iran. J. Org. Chem., 2016, 8:1703
37
[38]. Nabati M., Hojjati M. Iran. J. Org. Chem., 2016, 8:1777
38
[39]. Nabati M. Iran. J. Org. Chem., 2016, 8:1803
39
[40]. Nabati M. Iran. J. Org. Chem., 2016, 8:1817
40
[41]. Maurer R.I., Blower P.J., Dilworth J.R., Reynolds C.A., Zheng Y., Mullen G.E.D. J. Med. Chem., 2002, 45:1420
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47
ORIGINAL_ARTICLE
Investigation of NMR Parameters of para-Sulfonato-calix[4]arene by HF Calculation
Conformationally-rigid para-sulfonato-calix[4]arene (C28H24O16S4) was isolated. The NMR parameters of the structure of calix[4]arenes have been compared. The study of organic structures to form nanoporous materials is a well-known chemical phenomena (supermolecular chemistry) that is necessary for finding the crystal forms of calix[4]arenes. We investigated and compared the hydrogen bonding, oxygen, and sulfur atom effects on calix[4]arene via Hartree-fock(HF) theory by the Gaussian 98 of program package.
https://www.chemmethod.com/article_63198_60fcbf95c00f8230f12ba7492638ed69.pdf
2018-07-01
239
246
10.22034/chemm.2018.63198
Calix[4]arene
DFT
HF
Hydrogen bonding
Nanostructure
Chemical shift
Masoumeh
Sayadian
m_sayadian@iiau.ac.ir
1
Department of Chemistry, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran
AUTHOR
Hamidreza
Sadegh
hamid-sadegh@zut.edu.pl
2
West Pomeranian University of Technology, Szczecin, Faculty of Chemical Technology and Engineering, Division of Functional Materials and Biomaterials, Al. Piastow 45, Szczecin, Poland
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ORIGINAL_ARTICLE
New Organic Compounds Based on Biphenyl for Photovoltaic Devices: DFT Theoretical Investigation
Because of the specific characteristics of the π -conjugated molecules, they have become the most promising materials for the solar cell devices. To better grasp and anticipate of the π -conjugated compound, we have realized the study by using the DFT and ZINDO quantum chemical calculations. The purpose of the study of these compounds is to determine the geometries, electronic and optic properties by using the density functional theory (DFT/B3LYP) level with the correlation-consistent basis set 6-31G. On the other side, various physical parameters (HOMO, LUMO, Egap, Voc, λabs) were determined from the fully optimized structures. All This fundamental information will lead to propose new promising materials for organic solar cells.
https://www.chemmethod.com/article_63678_9bb017068d0de7d9e07639ffd2a29998.pdf
2018-07-01
247
259
10.22034/chemm.2018.63678
π-conjugated molecules
organic solar cells
density function theory (DFT)
low band-gap
Electronic properties
Wafae
Saidi
wafae.saidi@hotmail.fr
1
MEM, Faculty of Sciences, University Moulay Ismail, Meknes, Morocco
AUTHOR
Tayeb
Abram
tayeb87abram@gmail.com
2
MEM, Faculty of Sciences, University Moulay Ismail, Meknes, Morocco
AUTHOR
Lahcen
Bejjit
bejjitl@yahoo.fr
3
MEM, Faculty of Sciences, University Moulay Ismail, Meknes, Morocco
AUTHOR
Mohammed
Bouachrine
bouachrine@gmail.com
4
ESTM, Moulay Ismail University, Meknes, Morocco
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ORIGINAL_ARTICLE
Eutectic Mixture Choline Chloride–Chloroacetic acid: a New and Efficient Catalyst for Synthesis of 3,4-Dihydropyrimidin-2-ones
Deep Eutectic Solvents (DES) with the properties of an ionic liquid can be formed between choline chloride and chloroacetic acid in a 1:1 molar ratio. In this paper, we discuss our success in synthesizing dihydropyrimidinones employing choline chloride: chloroacetic acid as catalyst. The advantage of using DES is in its ability to act as a solvent and catalyst simultaneously for the synthesis of dihydropyrimidinones via one-pot multi-component reaction of ethyl acetoacetate, aldehyde and urea. The results showed that choline chloride: chloroacetic acid based DES is the best catalyst and is successfully applicable to a wide range of aldehydes with high yields (70–95%) and short reaction times (5-75 min). The deep eutectic solvent can be easily recycled and reused.
https://www.chemmethod.com/article_63681_c5b13ba663d73e26ffdbd178cf6d50b3.pdf
2018-07-01
260
269
10.22034/chemm.2018.63681
Deep eutectic
Choline chloride
Ionic Liquid
Dihydropyrimidinone
Biginelli rection
Ahmad reza
Momeni
ahmadrmomeni@yahoo.com
1
Faculty of Sciences, Shahrekord University, Shahrekord, Iran
LEAD_AUTHOR
Heshmat Allah
Samimi
h_samimi@yahoo.com
2
Faculty of Sciences, Shahrekord University, Shahrekord, Iran
AUTHOR
Hamed
Vaezzadeh
hamedvaezzadeh@yahoo.com
3
Faculty of Sciences, Shahrekord University, Shahrekord, Iran
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