Home Articles List Article Information
Chemical Methodologies
Journal Archive
Volume Volume 3 (2019)
Volume Volume 2 (2018)
Volume Volume 1 (2017)
Prasad, P., P, A., K, P., Sreedhar, N. (2018). Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples. Chemical Methodologies, 2(Issue 4. pp. 270-340), 277-290. doi: 10.22034/chemm.2018.63835
Puthalapattu Prasad; Aruna P; Prabhakar K; N.Y. Sreedhar. "Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples". Chemical Methodologies, 2, Issue 4. pp. 270-340, 2018, 277-290. doi: 10.22034/chemm.2018.63835
Prasad, P., P, A., K, P., Sreedhar, N. (2018). 'Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples', Chemical Methodologies, 2(Issue 4. pp. 270-340), pp. 277-290. doi: 10.22034/chemm.2018.63835
Prasad, P., P, A., K, P., Sreedhar, N. Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples. Chemical Methodologies, 2018; 2(Issue 4. pp. 270-340): 277-290. doi: 10.22034/chemm.2018.63835

Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples

Article 2, Volume 2, Issue 4. pp. 270-340, Autumn 2018, Page 277-290  XML PDF (1.19 MB)
Document Type: Original Article
DOI: 10.22034/chemm.2018.63835
Authors
Puthalapattu Prasad email 1; Aruna P1; Prabhakar K2; N.Y. Sreedhar1
1Electroanalytical Lab, Department of Chemistry, Sri Venkateswara University, Tirupati-517502, A.P., India.
2Department of Chemistry, D.K.W Govt. Degree College, Nellore, A.P., India.
Receive Date: 14 November 2017,  Revise Date: 30 May 2018,  Accept Date: 19 June 2018 
Abstract
In this study, we report an effective electrochemical sensor of single-walled carbon nanotubes (SWCNTs)/Nafion glassy carbon electrode (SWCNTs/Nafion/GCE) for determination of dicapthon in water and agricultural food samples. The electroanalytical performance of SWCNTs/Nafion/GCE toward the reduction of dicapthon was analyzed via cyclic and differential pulse voltammetry. The optimum parameters like the effect of pH, concentration of dicapthon solution, scan rate, accumulation potential and accumulation time were thoroughly optimized. At electrochemical optimum conditions, voltammetric reduction peak exhibited a linear with the concentration of dicapthon from 0.2‒60.0 μgmL−1, with a detection limit of 0.036 μgmL−1. The modified electrochemical sensor showed good stability and reproducibility. The determination of dicapthon was examined with SWCNTs/Nafion/GCE in water and agricultural food samples.

Graphical Abstract

Effective SWCNTs/Nafion Electrochemical Sensor for Detection of Dicapthon Pesticide in Water and Agricultural Food Samples
Keywords
SWCNTs; Nafion; Dicapthon; Agricultural food and sensor
Main Subjects
Applied Chemistry
References
References

  1. Jaffrezic-Renault N. Sens., 2001, 1:60
  2. Deo R.P., Wang J., Block I., Mulchandani A., Joshi K.A., Trojanowicz M., Scholz F., Chen W., Lin Y.H. Anal. Chim. Acta., 2005, 530:185
  3. Liu G., Lin Y. Anal. Chem., 2005, 77:5894
  4. Jiang W., Conkle J.L.,  Luo Y., Li J., Xu K., Gan J., Environ. Sci. Technol., 2016, 50:12592
  5. Pawlak M.K. Pol. J. Environ. Stud., 2004, 13:411
  6. Wei Y., Yang R., Guo Z., Gao Ch., Wang L., Liu J.H., Huang X.J. Anal. Methods., 2012, 4:353
  7. Zelayaran Melgar L., Machado S.A.S., J. Braz. Chem. Soc., 2005, 16:743
  8. Ahmadi F., Jafari B. Electroanalysis, 2011, 23:675
  9. Sreedhar N.Y., Prasad P.R., Reddy C.N., Prasad K.S. J. Nanosci. Nanotechnol., 2011, 1:6
  10. Diagne R.G., Foster G.D., Khan S.U. J. Agric. Food. Chem., 2002, 50:3204
  11. Aparna D., Seethamma G., Vijayalakshmi K.M., Kumar N.V.N. Am. Eur. Asian J. Agric. Environ. Sci., 2010, 7:657
  12. Harshit D., Charmy K., Nrupesh P. Food Chemistry, 2017, 230:448
  13. Arrebola F.J., Egea-Gonzalez F.J., Moreno M., Fernandez-Gutierrez A., Hernandez-Torres M.E., Martín-Vidal J.L.  Pes. Manage. Sci., 2001, 57:645 
  14. Martinez-Vidal J.L, Arrebola F.J., Fernandez-Gutiérrez A., Rams M.A. J. Chromatogr. B: Bio. Sci. Appl., 1998, 719:71
  15. Pablos-Espada M.C., Arrebola-Liebanas F.J., Garrido-Frenich A. Martinez-Vidal J.L. Int. J. Envir. Analy.Chem., 1999, 75:165
  16. Gebreegzi Y.T., Foster G.D., Khan S.U., J. Agric. Food Chem. 2000, 48:5165
  17. Sanchez M.E., Mendez R., Gomez X., Martin‐Villacorta J. J. Liq. Chromatogr. Related Technol. 2003, 26:483
  18. G. Erdogdu, J. Anal. Chem. 2007, 62:466 (https://doi.org/10.1134/S1061934807050139)
  19. Gu H.Y., Yu A.M., Chen H.Y., Anal. Lett. 2001, 34:2361
  20. Mazloumardakani M., Ebrahimi Karami E., Naeimi H., Mirjalili B., Turk J. Chem. 2008, 32:571
  21. Tefera M., Tessema M., Admassie S., Mehretie S., Anal. Bioanal. Chem. Res., 2015, 2:139
  22. Raoof J.B., Ojani R., Baghayeri M., Turk J. Chem. 2013, 37:36
  23. Sreeja V., Sasikumar R., Alagarsamy M., Manisankar P. Am. J. Anal. Chem., 2011, 2:814
  24. Joshi K.A., Tang J., Haddon R., Wang J., Chen W., Mulchandani A. Electroanalysis, 2005, 17:54
  25. Punbusayakul N. Procedia Engineering, 2012, 32:683
  26. Wang J., Musameh M., Lin Y. J. Am.Chem. Soc., 2003, 125:2408
  27. Manisankar P., Sundari P.L.A., Sasikumar R., Roy D.J. Electroanalysis, 2008, 20:2076
  28. Ngai K.S., Tan W.T., Zainal Z., Zawawi R.M., Zidan M. Int. J. Electrochem. Sci., 2013, 8:10557
  29. Zhu S., Li H., Niu W., Xu G. Biosens. Bioelectron., 2009, 25:940
  30. Wang H., Liu M., Hu X., Li M., Xiong X. Sens. 2013, 13:16234
  31. Zhao X.D., Fan X.H., Chen X.F., Chai C.P., Zhou Q.F. J. Polym. Sci., 2006, 44:4656
Statistics
Article View: 279
PDF Download: 308