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Document Type : Original Article


1 Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

2 Ph.D Educated, Department of Chemistry,Payamenoor University, Mashhad, Iran

3 Institute of Physic ASCR, v. v. i., Na Slovance 2, 182 21, Prague, Czech Republic



In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.

Graphical Abstract

Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands


Main Subjects

[1] Li M.N., Zhang L.Z., Yang M., Niu J.Y., Zhou J. Bioorg. Med. Chem. Lett., 2012, 22:2418
[2] Stanojkovic T.P., Kovala-Demertzi D., Primikyri A., Garcia-Santos I., Castineiras A., Juranic Z., Demertzis M.A. J. Inorg. Biochem., 2010, 104:467
[3] Alomar K., Landreau A., Kempf M., Khan M.A., Allain M., Bouet G. J. Inorg. Biochem., 2010, 104:397
[4] McCall K.A., Huang C., Fierke C.A. J. Nutr., 2000, 130:1437S
[5] Komatsu H., Ochiai B., Hino T., Endo T. J. Mol. Catal. A, 2007, 273:289
[6] Khalaji A.D., Grivani G., Seyyedi M., Fejfarova K., Dusek M. Polyhedron, 2013, 49:19
[7] Khalaji A.D., Grivani G., Seyyedi M., Fejfarova K., Dusek M. Acta Crystallogr., 2012, E68:m971
[8] Khalaji A.D., Grivani G., JalaliAkerdi S., Stoeckli-Evans H., Das D. J. Chem. Crystallogr., 2012, 42:83
[9] Khalaji A.D., Fejfarova K., Dusek M. Iran. J. Cryst. Miner., 2013, 21:1
[10] Khalaji A.D., Grivani G., Rezaei M., Fejfarova K., Dusek M. Phos. Sulf. Sil., 2013, 188:1119
[11] Guha A., Sanyal R., Chattopadhyay T., Han Y.G., Mondal T.K., Das D. J. Mol. Struct., 2013, 1042:104
[12] Saeednia S., Iranmanesh P., HatefiArdakani M., Mohammadi M., Norouzi G. Mater. Res. Bull., 2016, 78:1.
[13] Basak S., Sen S., Banerjee S., Mitra S., Rosair G., Garland Rodriguez M.T. Polyhedron, 2007, 26:5104
[14] Ravichandran J., Gurumoothy P., Karthick C., KalilurRahiman A. J. Mol. Struct., 2014, 1062:147
[15] Di Serio M., Carotenuto G., Cucciolito M.E., Lega M., Ruffo F., Tesser R., Trifuoggi M. J. Mol. Catal. A, 2012, 353-354:106
[16] Komatsu H., Ochiai B., Hino T., Endo T. J. Mol. Catal. A, 207, 273:289
[17] Lee S.K., Tan K.W., Ng S.W., Ooi K.K., Ang K.P., Abdah M.A. Spectrochim. Acta A, 2014, 121:101
[18] Montazerozohori M., MojahediJahromi S., Masoudiasl A., McArdle P., Spectrochim. Acta A, 2015, 138:517
[19] Shahsavani E., Khalaji A.D., Feizi N., Das D., Matalobos J.S., Kucerakova M., Dusek M. Superlat. Microstruct., 2015, 82:18
[20] Palatinus L., Chapuis G. J. Appl. Cryst.., 2007, 40:786
[21] Petricek V.,Dusek M., Palatinus L. Z. Kristallogr., 2014, 229:345
[22] Diamond – Crystal and Molecular Structure Visualization Crystal Impact – K. Brandenburg &
H. Putz GbR, Rathausgasse 30, D-53111 Bonn, 2012