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Document Type : Original Article


Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran



In this paper, nano-sized of two mercury(II) complexes with the general formula of HgLX2 (X=Br (1) and I (2)), L=N,N¢-bis{(paramethylamino)benzylidene}ethylenediamine have been prepared by ultrasonic bath assisted from the reaction of HgX2 and L in molar ratio 1:1 in methanol solution. The complexes were characterized by elemental analyses (CHN) and FT-IR spectroscopy, XRD and SEM. In addition, thermal stability of complexes was studied.

Graphical Abstract

Nano-sized Mercury(II) Schiff Base Complexes: Synthesis, Characterization and Thermal Studies


Main Subjects

[1] Mahmoudi G., Morsali A. Cryst. Growth Des., 2008, 8:391
[2] Basu Baul T.S., Kundu S., Mitra S., Hopfl H., Teikink E.R.T., Linden A. Dalton Trans., 2013, 42:1905
[3] Montazerozohori M., Mojahedi Jahromi S., Masoudiasl A., McArdle P. Spectrochim. Acta A, 2015, 138:517
[4] Di Serio M., Carotenuto G., Cucciolito M.E., Lega M., Ruffo F., Tesser R., Trifuoggi M. J. Mol. Catal., 2012, 353-354:106
[5] Motazerozohori M., Sedighipoor M. Spectrochim. Acta A, 2012, 96:70
[6] Montazerozohori M., Yadegari S., Naghiha A., Veyseh S. J. Ind. Eng. Chem., 2014, 20:118
[7] Montazerozohori M., Zahedi S., Naghiha A., Motazer Zohour M. Mat. Sci. Eng. C, 2014, 35:195
[8] Dong Y.W., Fan R.Q., Wang P., Wei L.G., Wang X.M., Gao S., Zhang H.J., Yang Y.L., Wang Y.L. Inorg. Chem., 2015, 54:7742
[9] Amiri M.G., Mahmoudi G., Morsali A., Hunter A.D., Zeller M. Cryst. Eng. Commun. 2007, 9:686
[10] Motazerozohori M., Mojahedi Jahromi S., Naghiha A. J. Ind. Eng. Chem., 2015, 22:248
[11] Zare Karizi F., Safarifard V., Karbalaei Khani S., Morsali A. Ultrason. Sonochem., 2015, 23:238
[12] Parast M.S.Y., Morsali A. J. Inorg. Organomet. Polym., 2012, 22:998
[13] Sheikhshoaiea I., Sheikhshoaie M., Ramezanpour S. Chem. Methodol., 2018, 2:103
[14] Sheikhshoaie I., Tohidiyan Z. Chem. Methodol., 2019, 3:30
[15] Khalaji A.D., Peyghoun S.J., Akbari A., Feizi N., Dusek M., Eigner V. Polyhedron, 2016, 119:429