@article { author = {Taghavi, Reza and Rostamnia, Sadegh}, title = {Four-Component Synthesis of Polyhydroquinolines via Unsymmetrical Hantzsch Reaction Employing Cu-IRMOF-3 as a Robust Heterogeneous Catalyst}, journal = {Chemical Methodologies}, volume = {6}, number = {9}, pages = {639-648}, year = {2022}, publisher = {Sami Publishing Company}, issn = {2645-7776}, eissn = {2588-4344}, doi = {10.22034/chemm.2022.340599.1511}, abstract = {In this report, an IRMOF-3 was synthesized via a solvothermal method and then used as support for stabilizing Cu(II) ions. Characterization methods such as FT-IR, XRD, SEM, and BET were employed to analyze produced Cu@IRMOF-3, demonstrating that the suggested catalyst effectively conserved its structure throughout the synthesis processes. The FT-IR results indicate that the presence of the -NH2 group in the structure of the MOF helped stabilize the Cu(II) ions. The manufactured catalyst was used to prepare polyhydroquinoline derivatives which showed superior results.}, keywords = {Metal-organic Frameworks,Polyhydroquinoline, IRMOF-3, Unsymmetrical Hantzsch reaction}, url = {https://www.chemmethod.com/article_151361.html}, eprint = {https://www.chemmethod.com/article_151361_497ec68336fe6b899ece540616665a1a.pdf} }