Synthesis and Characterization of Nano Sized ZnO and CdO by Direct Thermal Decomposition of Their Nano Sized Metal Schiff base Complexes

Sheikhshoaie, Iran; Sheikhshoaei, Mahdiye; Ramezanpour, Samaneh

doi:10.22034/chemm.2018.60129

Document Type : Original Article

Authors

¹ Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, 76175, Iran

² Young Research Society, Shahid Bahonar University of Kerman, Kerman, Iran

https://doi.org/10.22034/chemm.2018.60129

Abstract

Nano sized metal oxide; ZnO and CdO have been synthesized by the thermal decomposition of two Schiff base complexes. Zinc and cadmium Schiff base complexes have been synthesized at reflux condition by the reaction between bidentate Schiff base ligand (E)-2-((4-methoxyphenylimino) methyl) phenol and nitrate salts of Zn or Cd in acetonitrile as a solvent. The nanoparticles of the title complexes were obtained using the ultrasonic irradiation method in acetonitrile as an anti-solvent of the Zn and Cd metal complexes, and also using spectroscopy and physicochemical methods including FT-IR, UV-Vis, elemental analysis, X-ray powder diffraction (XRD) and scanning electron spectroscopy (SEM). The .nanoparticles (NPs) of ZnO and CdO with the average size of 27 and 32 nm were prepared by thermal decomposition of the title nano metal complexes. The metal oxide was identified by XRD pattern and SEM images.

Graphical Abstract

Keywords

Main Subjects

Synthesis of nanomaterials

Full Text

Google Scholar

References

[1] Yasrebi S.A., Mobasheri H., Sheikhshoaie I.,Rahban M. Inorganica Chim. Acta, 2013, 400:222.

[2] Xi P.X., Xu Z.H., Liu X.H., Cheng F.J.,Zeng Z.Z. Spectrochimica Acta Part A: Mole. Biomole. Spectro., 2008, 71:523.

[3] Sheikhshoaie I., Rezaeifard A., Monadi N.,Kaafi S. Polyhedron, 2009, 28:733.

[4] Holm R. Coord. Chem. Rev., 1990, 100:183.

[5] Rezaeifard A., Sheikhshoaie I., Monadi N.,Stoeckli‐Evans H. Eur. J. Inorg. Chem., 2010, 2010:799.

[6] Tamami B., Ghasemi S. Appl. Catal., A.Gen., 2011, 393:242.

[7] Tohidiyan Z., Sheikhshoaie I.,Khaleghi M., 2016.

[8] Beitollahi H.,Sheikhshoaie I. Int. J. Electrochem. Sci, 2012, 7:7684.

[9] Yu K., Gu Z., Ji R., Lou L.-L., Ding F., Zhang C.,Liu S. J. Catal., 2007, 252:312.

[10] Najafpour M.M., Heidari S., Amini E., Khatamian M., Carpentier R., Allakhverdiev S.I. J. Photochem. Photobi. B: Bio., 2014, 133:124.

[11] Geng L., Zhao Y., Huang X., Wang S., Zhang S., Huang W.,Wu S. Synth. Met., 2006, 156:1078.

[12] Wang D., Zhang J., Luo Q., Li X., Duan Y.,An J. J. Hazard. Mat., 2009, 169:546.

[13] Zhao Y., Li X.G., Zhou X.,Zhang Y.N. Sensors Actuators B: Chem., 2016, 231:324.

[14] Maisel A.S., Krishnaswamy P., Nowak R.M., McCord J., Hollander J.E., Duc P., Storrow A.B., Abraham W.T.,Wu A.H. N. Engl. J. Med., 2002, 347:161.

[15] Kim Y.S., Tai W.P.,Shu S.J. Thin Solid Films, 2005, 491:153.

[16] Vayssieres L. Adv. Mater., 2003, 15:464.

[17] Ennaoui A., Weber M., Scheer R., Lewerenz H. Sol. Energy Mater. Sol. Cells, 1998, 54: 77.

[18] Thema F., Beukes P., Gurib-Fakim A.,Maaza M. J. Alloys Compd., 2015, 646:1043.

[19] Kondo R., Okimura H.,Sakai Y. Jpn. J. Appl. Phys., 1971, 10:1547.

[20] Rakhshani A. Solid-State Electron., 1986, 29:7.

[21] Cheng B., Samulski E.T. Chem. Commun., 2004, 2004:986.

[22] Suchanek W.L. J. Cryst.Growth, 2009, 312:100.

[23] Yathisha R., Nayaka Y.A.,Vidyasagar C. Mater. Chem. Phys., 2016, 181:167.

[24] Senthil T.,Anandhan S. J. Colloid Interface Sci., 2014, 432:285.

[25] Khanpour M., Morsali A.,Retailleau P. Polyhedron, 2010, 29:1520.

[26] Sheikhshoaie I.,Mashhadizadeh M. Russ. J. Coord. Chem., 2003, 29:710.

[27] Sheikhshoaie I., Belaj F., Fabian W.M. J. Mole. Struct., 2006, 794:244.

[28] Takjoo R., Mague J.T., Akbari A., Ebrahimipour S.Y. J. Coord. Chem., 2013, 66:2852.

[29] Raman N., Raja Y.P. Kulandaisamy A., 2001.

[30] Golcu A., Tumer M., Demirelli H.,Wheatley R.A. Inorg. Chimica Acta, 2005, 358:1785.

[31] Ramezanpour S., Sheikhshoaie I.,Khatamian M. J.Mole. Liquids, 2017, 231:64.

[32] Sheikhshoaie I., Ramezanpour S., Khatamian M. J. Mole. Liquids, 2017, 238:248.

[33] Mahamuni S., Borgohain K., Bendre B., Leppert V.J.,Risbud S.H. J. Appl. Phys, 1999, 85:2861.

[34] Ristić M., Popović S., Musić S. Mater. Let., 2004, 58:2494.

Chemical Methodologies

Synthesis and Characterization of Nano Sized ZnO and CdO by Direct Thermal Decomposition of Their Nano Sized Metal Schiff base Complexes

Full Text

Full Text

References

References

Volume 2, Issue 2 - Serial Number 2
April 2018
Pages 103-113

Synthesis and Characterization of Nano Sized ZnO and CdO by Direct Thermal Decomposition of Their Nano Sized Metal Schiff base Complexes

Full Text

Full Text

References

References

Volume 2, Issue 2 - Serial Number 2April 2018Pages 103-113

Volume 2, Issue 2 - Serial Number 2
April 2018
Pages 103-113